REFERENCES
1. Khan, M. A.; Thatipamula, S.; Tresca, L.; Xu, L.; Trewartha, A.; Onori, S. High-power lithium-ion battery characterization dataset for stochastic battery modeling. Sci. Data. 2025, 12, 1506.
2. Park, G.; Park, N.; Ryu, J.; et al. Zero-strain Mn-rich layered cathode for sustainable and high-energy next-generation batteries. Nat. Energy. 2025, 10, 1215-25.
3. Chacana-olivares, J.; Peceño, B.; Grageda, M.; Cruz, C.; Rojas, L. Lithium-ion battery recycling: a perspective on key challenges and opportunities. npj. Mater. Sustain. 2025, 3, 38.
4. Hu, J.; Fu, P.; Wei, Z.; et al. Early prediction of lithium-ion battery degradation with a generative pre-trained transformer. Nat. Commun. 2025, 17, 126.
5. Chen, S.; Dai, F.; Cai, M. Opportunities and challenges of high-energy lithium metal batteries for electric vehicle applications. ACS. Energy. Lett. 2020, 5, 3140-51.
6. Xu, J.; Cai, X.; Cai, S.; et al. High-energy lithium-ion batteries: recent progress and a promising future in applications. Energy. Environ. Mater. 2023, 6, e12450.
7. Li, Y.; Zhang, J.; Chen, Q.; Xia, X.; Chen, M. Emerging of heterostructure materials in energy storage: a review. Adv. Mater. 2021, 33, 2100855.
8. Wang, S.; Zhao, S.; Guo, X.; Wang, G. 2D material-based heterostructures for rechargeable batteries. Adv. Energy. Mater. 2021, 12, 2100864.
9. Huang, S.; Wang, Z.; Von Lim, Y.; et al. Recent advances in heterostructure engineering for lithium-sulfur batteries. Adv. Energy. Mater. 2021, 11, 2003689.
10. Zhao, X.; Liu, M.; Wang, Y.; et al. Designing a built-in electric field for efficient energy electrocatalysis. ACS. Nano. 2022, 16, 19959-79.
11. Li, Y.; Wu, F.; Qian, J.; et al. Metal chalcogenides with heterostructures for high-performance rechargeable batteries. Small. Sci. 2021, 1, 2100012.
12. Gabriel, E.; Ma, C.; Graff, K.; Conrado, A.; Hou, D.; Xiong, H. Heterostructure engineering in electrode materials for sodium-ion batteries: recent progress and perspectives. eScience 2023, 3, 100139.
13. Mei, J.; Liao, T.; Sun, Z. 2D/2D heterostructures: rational design for advanced batteries and electrocatalysis. Energy. Environ. Mater. 2021, 5, 115-32.
14. Chen, L.; Ren, J. T.; Yuan, Z. Y. Enabling internal electric fields to enhance energy and environmental catalysis. Adv. Energy. Mater. 2023, 13, 2203720.
15. Fu, H.; Wen, Q.; Li, P. Y.; et al. Recent advances on heterojunction-type anode materials for lithium-/sodium-ion batteries. Small. Methods. 2022, 6, 2201025.
16. Zhou, W.; Lin, J.; Tang, Y.; et al. Catalyst for polysulfide conversion by Mo2C/MoO3 hybrids modified separator in lithium-sulfur batteries. Mater. Today. Phys. 2023, 37, 101193.
17. Oh, H. G.; Jang, S.; Kim, H. R.; et al. Interface-engineered 3D ZnTe/MXene heterostructures with built-in electric fields for fast and durable potassium storage. J. Energy. Chem. 2025, 111, 462-73.
18. Xie, J.; Li, Z.; Zheng, X.; Tian, F.; Lei, D.; Wang, C. Built-in electric field of in situ formed artificial interface layer induces fast and uniform sodium-ions transmission to achieve a long-term stable sodium metal battery under harsh conditions. Adv. Funct. Mater. 2024, 34, 2315309.
19. Cai, W.; Zhang, X.; Hu, J.; et al. Electrochemically activated α → β phase transition in space-confined MnO/MnSe-based heterostructure enabling exceptional Li/Na-ion storage. Small 2026, 22, e00045.
20. Cui, W.; Wang, P.; Li, X.; et al. Rich lattice defects Ni-MoO2/NiMoO4- bifunctional catalyst for efficient and stable seawater electrolysis hydrogen production. J. Mater. Sci. Technol. 2025, 235, 222-31.
21. Sun, S.; Han, Z.; Liu, W.; et al. Lattice pinning in MoO3 via coherent interface with stabilized Li+ intercalation. Nat. Commun. 2023, 14, 6662.
22. Liu, F.; Sun, X.; Liu, Y.; Song, X.; Gao, J.; Qin, G. TiO2 nanorods confined in porous V2O5 nanobelts and interconnected carbon channels for sodium ion batteries. Appl. Surf. Sci. 2019, 473, 873-84.
23. Le, T.; Yang, C.; Lv, W.; et al. Deeply cyclable and ultrahigh-rate lithium metal anodes enabled by coaxial nanochamber heterojunction on carbon nanofibers. Adv. Sci. 2021, 8, 2101940.
24. Xiong, P.; Zhang, F.; Zhang, X.; et al. Strain engineering of two-dimensional multilayered heterostructures for beyond-lithium-based rechargeable batteries. Nat. Commun. 2020, 11, 3297.
25. Chen, Y.; Fan, Q.; Wang, H.; et al. Heterostructured manganese-based cathode with atomic interlocking for advanced sodium-ion batteries. Adv. Energy. Mater. 2025, e04637.
26. Yang, M.; Lin, Y.; Chen, P.; et al. Unlocking ultrafast-kinetics asymmetric heterojunction with multi-anionic redox chemistry enables high energy/power density and low-temperature zinc-ion batteries. Angew. Chem. Int. Ed. 2025, 64, e202510907.
27. Gong, F.; Chen, Z.; Chang, C.; et al. Hollow Mo/MoSVn nanoreactors with tunable built-in electric fields for sustainable hydrogen production. Adv. Mater. 2024, 37, 2415269.
28. Jia, X.; Zhao, Y.; Bai, L. First-principles investigation of interfacial interactions of BP/Ti3C2S2 heterostructure regulating the anchoring performance in lithiumsulfur batteries. J. Energy. Storage. 2025, 132, 117859.
29. Yang, M.; Gong, K.; Cui, Y.; Liu, S.; Li, G.; Lin, S. Band engineering and structural-geometrical engineering in 2D/3D van der Waals heterostructures for advanced photodetection and intelligent sensing. Nano-Micro. Lett. 2026, 18, 298.
30. Liu, M.; Su, H.; Liu, X.; et al. Dynamic modulation of electron redistribution at the heterogeneous interface nickel hydroxides/platinum boosts acidic oxygen reduction reaction. Nat. Commun. 2025, 16, 2826.
31. Li, G.; Deng, F.; Ma, T.; et al. Integrating Ni2P crystalline-NiFeBP amorphous heterojunction nanosheets on hierarchical nickel foam for superior overall water splitting. Chem. Eng. J. 2025, 505, 159290.
32. Li, J.; Peng, X.; Liu, Z.; Tian, Y.; Wang, C. Defect-rich Zn2SnOx/SnOx heterostructure for high sulfur utilization and uniform Li+ transport toward stable Li-S full batteries. Nano. Res. 2026, 19, 94908323.
33. Zhang, W.; Li, L.; Wang, Q.; et al. Electrochemical performance of MoB/Si3N4 Heterojunction as a potential anode material for Li ion batteries. ACS. Appl. Mater. Interfaces. 2024, 16, 62155-70.
34. Aravind, A. M.; Tomy, M.; Kuttapan, A.; Kakkassery Aippunny, A. M.; Suryabai, X. T. Progress of 2D MXene as an electrode architecture for advanced supercapacitors: a comprehensive review. ACS. Omega. 2023, 8, 44375-94.
35. Zang, S.; Hu, C.; Nie, L.; et al. Research progress in anode materials based on multiple potassium storage mechanisms. Sustainable. Mater. Technol. 2022, 33, e00480.
36. Ye, J.; Wang, Z.; Liu, Q.; et al. Rational design of a setaria-like NiTe2/MoS2 semi-coherent heterogeneous interface for enhancing diffusion kinetics in potassium-ion batteries. J. Colloid. Interface. Sci. 2024, 674, 527-36.
37. Zhang, Y.; Liu, L.; Zhao, L.; et al. Sandwich-like CoMoP2/MoP heterostructures coupling N, P co-doped carbon nanosheets as advanced anodes for high-performance lithium-ion batteries. Adv. Compos. Hybrid. Mater. 2022, 5, 2601-10.
38. Ye, Y.; Chen, M.; Liu, S.; et al. Enhanced built-in electric field facilitates electron and ion transfer for high-performance lithium-sulfur batteries. ACS. Sustainable. Chem. Eng. 2025, 13, 20253-64.
39. Liu, S.; Chen, M.; Luo, Y.; et al. Synergistic electrochemical catalysis by high-entropy metal phosphide in lithium-sulfur batteries. J. Colloid. Interface. Sci. 2024, 669, 126-36.
40. Lai, C.; Chen, K.; Lei, M.; Hu, J.; Chen, S.; Li, C. Highly reversible iron fluoride conversion cathodes enabled by deep-eutectic solvent method and heterostructure design. Adv. Funct. Mater. 2024, 34, 2312415.
41. Xue, Y.; Luo, D.; Yang, N.; et al. Engineering checkerboard-like heterostructured sulfur electrocatalyst towards high-performance lithium sulfur batteries. Chem. Eng. J. 2022, 440, 135990.
42. Zhang, W.; Li, L.; Ren, J.; et al. Heterojunction engineering of conductive ability and structural stability for the electrochemical performance of MoB anode material. Journal. of. Energy. Storage. 2025, 112, 115589.
43. Zuo, X.; Qiu, Y.; Zhen, M.; Liu, D.; Zhang, Y. Review on MXenes-based electrocatalysts for high-energy-density lithium-sulfur batteries. Nano-Micro. Lett. 2025, 17, 209.
44. Javed, M. S.; Zhang, X.; Ali, S.; et al. Heterostructured bimetallic-sulfide@layered Ti3C2Tx-MXene as a synergistic electrode to realize high-energy-density aqueous hybrid-supercapacitor. Nano. Energy. 2022, 101, 107624.
45. Shah, S. A.; Pato, A. H.; Jangra, S.; et al. Emerging MXene/metal selenides for energy solutions: A comprehensive review. Nano. Research. 2025, 18, 94907855.
46. Zhang, N.; Meng, Q.; Wu, H.; et al. Co-MOF as stress-buffered architecture: an engineering for improving the performance of NiS/SnO2 heterojunction in lithium storage. Adv. Energy. Mater. 2023, 13, 2300413.
47. Lan, X.; Yang, S.; Meng, T.; Zhang, C.; Hu, X. A multifunctional electrolyte additive with solvation structure regulation and electrode/electrolyte interface manipulation enabling high-performance Li-ion batteries in wide temperature range. Adv. Energy. Mater. 2023, 13, 2203449.
48. Wang, C.; Zhang, Z.; Zheng, Y.; et al. Constructing face-shared configuration at the hetero-interface in Li-rich layered oxide cathodes. Angew. Chem. Int. Ed. 2026, 65, e2943336.
49. Yu, R.; Wang, G.; Wu, B.; et al. Synergistic energy band modulation and interfacial structure engineering for highly-reversible anionic redox in Li-rich Mn-based layered oxides. Energy. Storage. Mater. 2025, 80, 104447.
50. Zhu, Y.; Gu, J.; Zhang, G.; et al. A Si-MoSe2 heterostructured anode with enhanced thermal transport and electrochemical performance for liquid and all-solid-state lithium-ion batteries. Adv. Sci. 2026, 13, e23320.
51. Liu, M.; Guan, Z.; Zheng, L.; et al. Layered-to-rocksalt atomic reconfiguration on O3-type cathodes surface for high-energy and durable sodium-ion batteries. Mater. Today. 2025, 89, 35-43.
52. Geng, J.; Sun, C.; Xie, J.; et al. Topological transformation construction of a CoSe2/N-doped carbon heterojunction with a three-dimensional porous structure for high-performance sodium-ion half/full batteries. Inorg. Chem. Front. 2022, 9, 3176-86.
53. Chen, X.; Zeng, J.; Wu, J.; et al. Air stability and Na site activation of NASICON-based NFPP/NVOPF/C heterostructured cathode via surface reconstruction. Adv. Funct. Mater. 2025, 36, e11174.
54. Zhang, M.; Wang, S.; Zhu, J.; et al. Optimized heterostructures by preferred crystal orientation for ultrafast sodium storage. Adv. Funct. Mater. 2025, 35, 2500165.
55. Jiang, Y.; Lian, M.; Ma, J.; et al. Synchronous regulation of S-deficient ZnS-MoS2 heterostructure nanoreactor for fast and durable sodium storage. Nano. Lett. 2025, 25, 7241-8.
56. Song, L.; Zhang, S.; Duan, L.; et al. Tunable interfacial electric field-mediated cobalt-doped FeSe/Fe3Se4 heterostructure for high-efficiency potassium storage. Angew. Chem. Int. Ed. 2024, 63, e202405648.
57. Wang, T.; Li, M.; Qi, L.; Jie, P.; Yang, W.; Li, Y. Multilevel heterostructure of MoS2/GDYO for lithium-ion batteries. Adv. Funct. Mater. 2023, 33, 2308470.
58. Li, M.; Wang, C.; Wang, C.; et al. 10 years development of potassium-ion batteries. Adv. Mater. 2025, 37, 2416717.
59. Jia, X.; Chen, H.; Sun, H.; Zhu, J.; Lu, B. Promoting robust potassium storage via engineered Zn-S bond. Adv. Energy. Mater. 2025, 15, 2501487.
60. Wang, X.; Zhao, J.; Chen, Y.; et al. Yolk-shell MnSe/ZnSe heterostructures with selenium vacancies encapsulated in carbontubes for high-efficiency sodium/potassium Storage. Small 2023, 20, 2307747.
61. Li, Q.; Liang, Z.; Huang, Y.; et al. Tailoring self-catalytic N-Co bonds into heterostructure architectures: deciphering polytellurides conversion mechanism toward ultralong-lifespan potassium ion storage. Adv. Mater. 2025, 37, 2502894.
62. Wang, T.; He, J.; Zhu, Z.; et al. Heterostructures regulating lithium polysulfides for advanced lithium-sulfur batteries. Adv. Mater. 2023, 35, 2303520.
63. Hu, Y.; Chen, W.; Lei, T.; et al. Strategies toward high-loading lithium-sulfur battery. Adv. Energy. Mater. 2020, 10, 2000082.
64. Wang, T.; Tan, X.; Ma, Y.; Ma, Y.; Wu, Y. High-entropy materials regulating lithium polysulfides for advanced lithium-sulfur batteries. Chem. Eng. J. 2025, 519, 165580.
65. Wang, T.; Zhong, J.; Huang, X.; et al. Highly synergistic electrocatalysis and confinement of covalently bonded heterostructures enable high-efficient-stable Li-S batteries. Energy. Storage. Mater. 2025, 81, 104477.
66. Wang, T.; He, J.; Cheng, X.; Zhu, J.; Lu, B.; Wu, Y. Strategies toward high-loading lithium-sulfur batteries. ACS. Energy. Lett. 2022, 8, 116-50.
67. Song, H.; Nguyen, T. T.; Chu, R.; Bai, Y.; Kim, N. H.; Lee, J. H. Coupling interfacial effect in heterogeneous RuP2-RuP for accelerating sulfur reduction reaction of lithium sulfur batteries. Nano. Energy. 2024, 128, 109859.
68. Jiao, X.; Tan, L.; Tang, X.; et al. A 405 W h kg-1 Ah-level lithium-sulfur pouch battery stabilized over 200 cycles by an electron-triode-like GeS2-NiS2 heterostructure. Energy. Environ. Sci. 2025, 18, 4053-67.
69. Chen, B.; He, C.; Tao, Y.; et al. Lattice-confined single-atom Fe tunes co spin states for fast sulfur redox in Li S batteries. Chem. Eng. J. 2025, 525, 170280.
70. Huang, C.; Yu, J.; Zhang, C. Y.; et al. Electronic spin alignment within homologous NiS2/NiSe2 heterostructures to promote sulfur redox kinetics in lithium-sulfur batteries. Adv. Mater. 2024, 36, 2400810.
71. Yu, S.; Yin, L.; Zhang, C.; et al. Asymmetric cobalt sites induced low-spin state for enhanced redox kinetics in lithium-sulfur batteries. eScience 2026, 100552.
72. Liu, Y.; Li, L.; Li, X.; et al. Asymmetric tacticity navigates the localized metal spin state for sustainable alkaline/sea water oxidation. Sci. Adv. 2025, 11, eads0861.
73. Wang, T.; Yao, H.; Luo, Z.; et al. Interface-regulated bifunctional separator for highly robust lithium sulfur batteries. Mater. Today. 2026, 97, 103363.
74. Wu, G.; Fan, Y.; Li, J.; et al. Facilitated polysulfide redox conversion by delocalized electrons in MBene heterointerface for highly stable lithium-sulfur batteries. Nano-Micro. Lett. 2026, 18, 252.
75. Wang, T.; Shi, Z.; Xu, B.; et al. A thermally conductive separator for safe lithium metal batteries. ACS. Energy. Lett. 2026, 11, 3880-9.
76. Hao, M.; Xiong, X. G.; Li, Z.; et al. Adsorption-catalysis synergy boosting the conversion of polysulfide over mesoporous carbon confined molecular catalysts. Adv. Energy. Mater. 2025, 15, 2501226.
77. Ma, C.; Zhao, S.; Chen, H.; et al. Intimate heterostructured electrocatalyst for functional tandem catalysts of lithium polysulfides in separator-modified lithium-sulfur batteries. Carbon. Energy. 2025, 7, e70033.
78. Xu, G.; Song, X.; Jiang, M.; Wang, R.; Lian, S.; Yang, X. Synergistic promotion of reaction kinetics for LiPSs at high loadings by interfacial built-in electric field and sulfur vacancies of ternary heterostructure for high-performance Li-S batteries. Appl. Catal. B. Environ. 2025, 362, 124707.
79. Feng, J.; Li, Z.; Zhao, L.; et al. Built-in electric field and Te charge modulation in 2D Bi2Te3@Sb2Te3 heterostructure enable ultralong cycling for lithium-air batteries. Adv. Funct. Mater. 2025, 35, 2504803.
80. Sun, C.; Xiao, F.; Li, M.; et al. Partial-oxidation enabling homologous Ru/RuO2 heterostructures with proper d-dand center as efficient and durable cathode catalysts for ultralong cycle life in Li-O2 batteries. Adv. Energy. Mater. 2024, 15, 2402699.
81. Zhu, T.; Xia, C.; Wu, B.; et al. Inbuilt photoelectric field of heterostructured cobalt/iron oxides promotes oxygen electrocatalysis for high-energy-efficiency zinc-air batteries. Appl. Catal. B. Environ. 2024, 357, 124315.
82. Xia, Y.; Wang, L.; Gao, G.; et al. Constructed Mott-Schottky heterostructure catalyst to trigger interface disturbance and manipulate redox kinetics in Li-O2 battery. Nano-Micro. Lett. 2024, 16, 258.
83. Lu, Z.; Wang, Z.; Yang, Z.; et al. Engineering CoN4 and FeN4 dual sites with adjacent nanoclusters on flexible porous carbon fibers for enhanced electrocatalytic oxygen reduction and evolution. Adv. Funct. Mater. 2024, 35, 2418489.
84. Zhang, J.; Dong, X.; Wang, G.; Chen, J.; Wang, R. Interfacial engineering-induced Janus heterostructures with enhanced electronic regulation for efficient oxygen electrocatalysis in rechargeable Zn-air batteries. Appl. Catal. B-Environ. 2024, 342, 123459.
85. Xu, Z.; Chen, J.; Zhang, T.; et al. Enhancing efficiency and durability of alkaline Zn-Co/air hybrid batteries with self-reconstructed Co/Co2P heterojunctions. Adv. Energy. Mater. 2024, 15, 2402839.
86. Xu, Z.; Wu, J.; Chen, W.; et al. Plasma-assisted nitridation modulates the electronic structure of the NiSe2/Ni@Ni3N ternary heterojunction enhancing its dual-function catalytic performance and inhibiting zn dendrite growth in rechargeable zinc-air batteries. Adv. Funct. Mater. 2025, 35, e11117.
87. Zhang, S.; Chen, Q.; Zheng, L.; et al. Heteroengineered Fe2N/CrNx with accelerated proton-coupled electron transfer for efficient oxygen reduction in aluminum-air batteries. Adv. Mater. 2025, 38, e14607.
88. Wu, M.; Zhan, X.; Yang, S.; et al. The 2e- vs. 4e- pathways for ORR in rechargeable zinc-air batteries. Energy. Environ. Sci. 2026, 19, 1899-915.
89. Wan, Y.; Pei, M.; Tang, Y.; et al. Interfacial water regulation for nitrate electroreduction to ammonia at ultralow overpotentials. Adv. Mater. 2025, 37, 2417696.
90. Sun, S.; Huang, W.; Yu, H.; Sun, Z.; Shang, W.; Wen, Y. Constructing MXene@ZIF-67 core-shell heterostructures on mg anodes for a high-performance aqueous Mg battery. J. Alloys. Compd. 2025, 1016, 178899.
91. Yang, M.; Chuai, M.; Lai, M.; et al. Customizable crystalline-amorphous rectifying heterostructure cathodes for durable and super-fast zinc storage. Energy. Environ. Sci. 2025, 18, 4651-64.
92. Zheng, Z.; Ding, C.; Hasan, M. S.; et al. In-situ study of photo-rechargeable aqueous zinc-ion batteries with the bifunctional α-MnO2Photoelectrodes. Adv. Funct. Mater. 2025, 35, 2500182.
93. Zhao, X.; Zhang, F.; Li, H.; et al. Dynamic heterostructure design of MnO2 for high-performance aqueous zinc-ion batteries. Energy. Environ. Sci. 2024, 17, 3629-40.
94. Wang, T.; Wang, C.; Silva, G. V. D. O.; et al. Electrode interface engineering of hydrophilic and zincophilic bifunctionality for high-efficiency and low-polarization Zn anodes. Adv. Funct. Mater. 2024, 34, 2408662.
95. Chen, M.; Zhou, M.; Wang, Q.; et al. Desolvation effect triggered by TiS2-TiO2 heterostructure for ultrahigh-rate aqueous zinc-ion batteries. Adv. Funct. Mater. 2024, 35, 2414032.
96. Fu, Y.; Zhong, J.; Zhang, S.; et al. Interfacial electronic nanoarchitectonics for sustainable Zn-I2 batteries. Angew. Chem. Int. Ed. 2026, 65, e22065.
97. Jia, B.; Hu, E.; Hu, Z.; et al. Laminated tin-aluminum anodes to build practical aqueous aluminum batteries. Energy. Storage. Mater. 2024, 65, 103141.
98. Yang, Z.; Cheng, H.; Yang, W.; et al. Local microenvironment-induced dynamic self-adaptation for high-performance ammonium-ion batteries. ACS. Nano. 2025, 19, 37154-64.
99. Ran, Q.; Shi, H.; Meng, H.; et al. Aluminum-copper alloy anode materials for high-energy aqueous aluminum batteries. Nat. Commun. 2022, 13, 576.


