REFERENCES
1. Chen, H.; Wang, C.; Wu, H.; et al. Host-guest-induced electronic state triggers two-electron oxygen reduction electrocatalysis. Nat. Commun. 2024, 15, 9222.
2. Guo, B.; Jiang, Q.; Mao, Z.; et al. B-F dual-doped carbon nanotubes for multi-site and high-rate two-electron oxygen reduction reaction electrocatalysis. Carbon 2024, 222, 118997.
3. Mu, N.; Luo, Z.; Shan, W.; Huang, H.; Tang, H. Harnessing proton-coupled electron transfer in covalent organic frameworks for high-yield H2O2 photosynthesis. ACS. Sustain. Chem. Eng. 2025, 13, 16534-43.
4. Liu, Y.; Wei, B.; Yang, L.; Han, X.; Wang, Y.; Zhao, X. Recent research progress in hydrogen peroxide synthesized by electrocatalytic process with two-electron transfer: a brief review. J. Environ. Chem. Eng. 2024, 12, 112972.
5. Du, P.; Wang, R.; Deng, B.; et al. AC-electrochemical synthesis of H2O2 by breathing O2 in three-phase interface. Nano. Energy. 2024, 125, 109600.
6. Sun, M.; Zhang, G.; Qin, Y.; et al. Redox Conversion of chromium(VI) and arsenic(III) with the intermediates of chromium(V) and arsenic(IV) via AuPd/CNTs electrocatalysis in acid aqueous solution. Environ. Sci. Technol. 2015, 49, 9289-97.
7. Su, Y.; Shi, Y.; Jin, L.; et al. Unlocking the potential of MOFs for waste plastic resource utilization and microplastic pollution control. Sustain. Eng. Novit. 2026, 2, 4.
8. Eswaran, S. G.; Gao, Y.; Wang, A. Metal-organic frameworks: morphological diversity and applications of rod, sheet, cubic and octahedral structures. Sustain. Eng. Novit. 2026, 2, 5.
9. Fu, D.; Zhu, J.; Wang, L.; et al. Biradical-mediated synergistic electrocatalysis using metal-free redox molecular catalysts. Nat. Commun. 2025, 16, 11520.
10. Bera, A.; Bimmermann, S.; Gerschel, P.; et al. Mechanistic promiscuity in cobalt-mediated CO2 reduction reaction: one- versus two-electron reduction process. Angew. Chem. Int. Ed. 2025, 64, e202503705.
11. Xia, P.; Xu, T.; Niu, X.; et al. Regulating intermediate adsorption toward efficient two-electron oxygen reduction: fundamentals and perspectives. Electrochim. Acta. 2026, 563, 148696.
12. Du, X.; Li, X.; Li, J.; Sun, T. Achievement of transition metal chalcogenides/oxides in hydrogen production by seawater electrolysis. EcoEnergy 2026, e70072.
13. Wei, L.; Dai, J.; Qin, S.; et al. Two-dimensional materials for high-current-density seawater electrolysis. Green. Chem. 2025, 27, 8755-76.
14. Xu, R.; Zhu, Z.; Zhang, H.; et al. Synergistic material-structure engineering for mid-infrared thermal management in textiles. Small 2025, 21, e09257.
15. Sun, M.; Yuan, Z. Valorization strategies for electrodegradation of nitrogenous wastes in sewage. Acta. Phys. Chim. Sin. 2025, 41, 100108.
16. Qin, S.; Dai, J.; Tian, H.; et al. 3D printing driving innovations in extreme low-temperature energy storage. Virtual. Phys. Prototyping. 2025, 20, e2459798.
17. Ma, X.; Wu, Z.; Tian, H.; et al. Durable coaxial fiber-based underwater strain sensor with reversible dry-wet transition. InfoMat 2025, 7, e70030.
18. Song, H.; Liang, Y.; Zhang, G.; et al. Superhydrophobic wearable strain sensors: from strategic design to robustness paradigm. Nano. Micro. Lett. 2026, 18, 392.
19. Wang, W.; Ding, M.; Zhao, C. G.; et al. Unlocking migratory insertion in gold redox catalysis. Angew. Chem. Int. Ed. 2023, 62, e202304019.
20. Li, L.; Wang, B.; Chen, H.; et al. Organogel polymer electrocatalysts for two-electron oxygen reduction. Small 2024, 21, 2410371.
21. Song, M.; Liu, W.; Zhang, J.; Zhang, C.; Huang, X.; Wang, D. Single-atom catalysts for H2O2 electrosynthesis via two-electron oxygen reduction reaction. Adv. Funct. Mater. 2023, 33, 2212087.
22. Yang, H.; An, N.; Kang, Z.; Menezes, P. W.; Chen, Z. Understanding advanced transition metal-based two electron oxygen reduction electrocatalysts from the perspective of phase engineering. Adv. Mater. 2024, 36, 2400140.
23. Bernard, R. S.; Jha, A. K.; Kalek, M. Electrochemical oxidations through hypervalent iodine redox catalysis. Tetrahedron. Chem. 2024, 11, 100081.
24. Xie, Z.; Gupta, N.; Niklas, J.; et al. Photochemical charge accumulation in a heteroleptic copper(i)-anthraquinone molecular dyadvia proton-coupled electron transfer. Chem. Sci. 2023, 14, 10219-35.
25. Miller, D. C.; Tarantino, K. T.; Knowles, R. R. Proton-coupled electron transfer in organic synthesis: fundamentals, applications, and opportunities. Top. Curr. Chem. 2016, 374, 30.
26. Mondal, I.; Sheng, H.; Lee, K.; Jin, S.; Schmidt, J. R. Rationalizing the overall H2O2 selectivity of metal dichalcogenide electrocatalysts for the two-electron oxygen reduction reaction using microkinetic modeling. ACS. Catal. 2025, 15, 8788-98.
27. Zhao, G.; Chen, T.; Tang, A.; Yang, H. Roles of oxygen-containing functional groups in carbon for electrocatalytic two-electron oxygen reduction reaction. Chem. A. Eur. J. 2024, 30, e202304065.
28. Peng, W.; Liu, J.; Liu, X.; et al. Facilitating two-electron oxygen reduction with pyrrolic nitrogen sites for electrochemical hydrogen peroxide production. Nat. Commun. 2023, 14, 4430.
29. Jing, B.; Zhang, Q.; Liu, M.; et al. Magnetically-altered eg-orbital occupancy to boost the two-electron oxygen reduction electrocatalysis for faster water decontamination. Appl. Catal. B. Environ. Energy. 2025, 369, 125149.
30. Zhao, Y.; Raj, J.; Xu, X.; Jiang, J.; Wu, J.; Fan, M. Carbon catalysts empowering sustainable chemical synthesis via electrochemical CO2 conversion and two-electron oxygen reduction reaction. Small 2024, 21, 2311163.
31. Shou, W.; Zhao, W.; Liu, Y.; Wang, T. Toward rational understanding of the hydrogen evolution polarization curves through multiscale simulations. Nat. Commun. 2025, 17, 802.
32. Zhang, Z.; Li, J.; Wang, Y. Modeling interfacial dynamics on single atom electrocatalysts: explicit solvation and potential dependence. Acc. Chem. Res. 2024, 57, 198-207.
33. Yu, A.; Liu, S.; Yang, Y. Recent advances in electrosynthesis of H2O2 via two-electron oxygen reduction reaction. Chem. Commun. 2024, 60, 5232-44.
34. Zhu, L.; Yao, H.; Sun, L.; Ai, L.; Zhai, H.; Yi, C. Alloyed rhodium-copper nanocavities with optimized chemisorption of hydrogen radicals for efficient nitrate-to-ammonia electrocatalysis. Small 2025, 21, 2502787.
35. Jiang, S.; Zhang, L.; Yu, H.; et al. Heterostructure and interface engineering of Ni0.85Se-MoSe2@PEI for enhancing electrocatalytic acidic oxygen reduction to hydrogen peroxide. Chem. Eng. J. 2024, 489, 151272.
36. Mei, X.; Zhao, X.; Du, H.; et al. Adjusting the active site of single Co atoms on CeO2 via cyano functional groups for selective H2O2 electrosynthesis at high yield. Appl. Catal. B. Environ. Energy. 2025, 374, 125398.
37. Xu, X.; Xu, R.; Zhao, Y.; et al. Boron-doped biomass carbon nanostructures as electrocatalysts for the two-electron oxygen reduction reaction. ACS. Appl. Nano. Mater. 2024, 7, 18912-9.
38. Li, Z.; Jia, J.; Sang, Z.; et al. A computation-guided design of highly defined and dense bimetallic active sites on a two-dimensional conductive metal-organic framework for efficient H2O2 electrosynthesis. Angew. Chem. Int. Ed. 2024, 63, e202408500.
39. Zuo, L.; Deng, Y.; Chen, L.; He, T.; Yang, J.; Zhang, J. Fundamental insights into photoelectrochemical carbon dioxide reduction: elucidating the reaction pathways. ACS. Catal. 2024, 14, 16795-833.
40. Li, Y.; Sun, X.; Liu, M.; et al. Self-hydroxylated iron oxyhydroxide nanoislands boosting near-unity two-electron oxygen reduction selectivity over conductive MOFs. Chem. Eng. J. 2024, 494, 153132.
41. Guo, Q.; Huang, B.; Bo, G.; et al. Molecular engineering of wastewater nickel into single-site electrocatalysts for hydrogen peroxide production with industrial level current. Angew. Chem. Int. Ed. 2025, 137, e202514519.
42. Song, J.; Yu, J. M.; Ahn, J. H.; et al. Selective, stable, bias-free, and efficient solar hydrogen peroxide production on inorganic layered materials. Adv. Funct. Mater. 2022, 32, 2110412.
43. Perry, S. C.; Pangotra, D.; Vieira, L.; et al. Electrochemical synthesis of hydrogen peroxide from water and oxygen. Nat. Rev. Chem. 2019, 3, 442-58.
44. Li, X.; Xu, W.; Le, L. Q.; et al. Sulfur-modulated isolated NiNx sites toward electrocatalytic hydrogen peroxide generation. Chem. Catal. 2023, 3, 100724.
45. Ahn, S. M.; Lee, S.; Lee, G.; et al. Hydroxyl-blocking lignin-derived carbon catalysts for selective and durable hydrogen peroxide electrosynthesis. Appl. Catal. B. Environ. Energy. 2026, 390, 126606.
46. Xia, H.; Sun, H.; Yang, D.; et al. Curvature-engineered steering of oxygen electroreduction pathways on single-atom catalysts. Angew. Chem. Int. Ed. 2026, 138, e3924995.
47. Wang, Y.; Wang, Y.; Dong, Q.; et al. Boosting the electrochemical O2-to-H2O2 synthesis by revamping the FeMo catalyst with N/O co-doped surface. Chem. Eng. J. 2023, 460, 141673.
48. Zhang, S.; Wang, Y.; Jiang, C.; et al. Doped-Sn enhanced the performance of BiOCl nanosheet on electrocatalytic synthesis of hydrogen peroxide. Small 2024, 20, 2403862.
49. Yan, L.; Wang, C.; Wang, Y.; et al. Optimizing the binding of the *OOH intermediate via axially coordinated Co-N5 motif for efficient electrocatalytic H2O2 production. Appl. Catal. B. Environ. 2023, 338, 123078.
50. Xie, M.; Zheng, W.; Ren, Y.; Yu, H.; Liu, J.; Liu, Y. Steering pulsed electrochemistry selectivity toward singlet oxygen via dynamic intermediate management. Angew. Chem. Int. Ed. 2026, 138, e24903.
51. Yang, M.; Song, W.; Chen, C.; et al. Atomically dispersed Co/Mo sites anchored on mesoporous carbon hollow spheres for highly selective oxygen reduction to hydrogen peroxide in acidic media. Adv. Mater. 2025, 37, 2416401.
52. Wang, R.; Luo, H.; Duan, C.; et al. Crystal OH mediating pathway for hydrogen peroxide production via two-electron water oxidation in non-carbonate electrolytes. Nat. Commun. 2024, 15, 10456.
53. Yan, H.; Jiang, J.; Huang, Y.; et al. Inter-ring bonding electron donor structure triggers efficient two-electron water oxidation for photocatalytic hydrogen peroxide synthesis. Adv. Mater. 2025, 38, e07961.
54. Hu, X.; Jiang, H.; Chen, R.; et al. Breaking the scaling relationship in two-electron water oxidation via designing dual active centers for efficient H2O2 electrosynthesis. ACS. Catal. 2025, 15, 8403-13.
55. Dong, X.; Shi, W.; Tao, S.; Chen, Y.; Zhang, J. Constructing frustrated Lewis acid-base Cu···N pairs on Pd metallene toward efficient oxygen reduction reaction. DeCarbon 2026, 12, 100163.
56. Hong, S.; Yuan, L.; Liu, S.; et al. Unusual fullerene-like curved surface with unique Fe-N4 sites for highly efficient oxygen reduction reaction in zinc-air battery. Innov. Energy. 2026, 3, 100154.
57. Yan, Y.; Yang, H.; Zhou, T.; et al. Fe-free photocatalysis-self-fenton system for ultraefficient water purification enabled by carbon nitride with strong built-in electric field. EcoEnergy 2026, 4, e70044.
58. Hao, A.; Qiu, X.; Ye, Y.; et al. Constructing amorphous ZnCdS/Bi4Ti3O12-Ov heterostructure for enhancing piezocatalytic coupled Fenton-like reaction toward efficient wastewater purification and unraveling the mechanism. Mater. Futures. 2026, 5, 035101.
59. Wang, K.; Zhang, X.; Lyu, J.; et al. Recent progress of dual-atom catalysts on zinc-air batteries. Nano. Mater. Sci. 2026, 8, 585-611.
60. Ling, C.; Jin, D.; Li, R.; Li, C.; Wang, W. Self-assembled membranes modulate the active site of carbon fiber paper to boost the two-electron water oxidation reaction. Chem. Eng. J. 2023, 465, 142903.
61. Liang, Z.; Lei, H.; Zheng, H.; et al. Selective two-electron and four-electron oxygen reduction reactions using Co-based electrocatalysts. Chem. Soc. Rev. 2025, 5411, 5248-91.
62. Zhu, K.; Shou, W.; Jia, B.; et al. Sponge-inspired catalyst design for durable acidic CO2 reduction at low K+ concentration. Nat. Commun. 2026, 17, 5763.
63. Jiang, T.; Qin, X.; Ye, K.; et al. An interactive study of catalyst and mechanism for electrochemical CO2 reduction to formate on Pd surfaces. Appl. Catal. B. Environ. 2023, 334, 122815.
64. Li, Z.; Wei, X.; Zhu, Z.; et al. Synthesis, characterizations, and structure-activity relationship of dual-atom catalysts for CO2 electroreduction. DeCarbon 2025, 9, 100112.
65. Yang, Z.; Li, X.; Cui, X.; Zheng, Z.; Zheng, P.; Zhang, Y. Integrated strategies toward the capture and electrochemical conversion of low-concentration carbon dioxide. Exploration 2025, 5, e20240006.
66. Chen, R.; Wu, Q.; Luo, J.; Zu, X.; Zhu, S.; Sun, Y. Defective ultrathin two-dimensional materials for photo-/electrocatalytic CO2 reduction: fundamentals and perspectives. Acta. Phys. Chim. Sin. 2025, 41, 100019.
67. Wang, F.; Wang, B.; Zhang, T.; Liu, J. Electrochemical CO2 reduction to C3+ products: a review. Green. Carbon. 2026, 4, 12-26.
68. Zhang, C.; Gu, Y.; Jiang, Q.; et al. Exploration of gas-dependent self-adaptive reconstruction behavior of Cu2O for electrochemical CO2 conversion to multi-carbon products. Nano. Micro. Lett. 2024, 17, 66.
69. Liu, H.; Zhang, Y.; Xu, Q.; et al. Carnot battery with thermochemical energy storage and supercritical CO2 power cycle: thermodynamic and techno-economic characteristics. Innov. Energy. 2026, 3, 100163.
70. Li, B.; Ruan, X.; Ravi, S. K. Polyoxometalates in photocatalytic CO2 reduction: multielectron redox regulation across molecular and hybrid architectures. EcoEnergy 2026, e70076.
71. Zhang, G.; Wang, Z.; Shi, D.; et al. Rational design of H2 production sites for achieving photoconversion of CO2 with H2O into widely adjustable syngas and highly effective H2 evolution. Green. Carbon. 2025, 3, 11-21.
72. Naveen, B.; Lee, S. Rational design of Cu@Pd core-shell nanostructures via galvanic replacement for dual electrochemical applications: hydrogen evolution and nitrate reduction reactions. Molecules 2025, 30, 4062.
73. Huang, C.; Triana, C. A.; Jia, B.; Erni, R.; Zhao, H.; Patzke, G. R. Operando tracking of the structural evolution of copper carbodiimide during electrocatalytic nitrate reduction. ACS. Catal. 2025, 15, 11407-16.
74. Bai, L.; Franco, F.; Timoshenko, J.; et al. Electrocatalytic nitrate and nitrite reduction toward ammonia using Cu2O nanocubes: active species and reaction mechanisms. J. Am. Chem. Soc. 2024, 146, 9665-78.
75. Zhang, L.; Wu, Y.; Zhu, Z.; et al. Synergistically enhancing nitrate reduction into N2 in water by N-doped Pd-Cu biochar bimetallic single-atom electrocatalysis. Biochar 2024, 6, 8.
76. Liu, M.; Lu, Z.; Yang, L.; et al. Co-N bond promotes the H* pathway for the electrocatalytic reduction of nitrate (NO3RR) to ammonia. J. Environ. Chem. Eng. 2023, 11, 109718.
77. Zhou, N.; Wang, Z.; Zhang, N.; Bao, D.; Zhong, H.; Zhang, X. Potential-induced synthesis and structural identification of oxide-derived Cu electrocatalysts for selective nitrate reduction to ammonia. ACS. Catal. 2023, 13, 7529-37.
78. Wang, Y.; Zeng, W.; Gong, Q.; Zhan, M.; Hao, X.; Peng, Y. Enhancing anaerobic ammonium oxidation via polymeric ferric sulfate (PFS)-mediated dual-electron Acceptor: a solution to nitrite deficiency. Chem. Eng. J. 2024, 498, 155199.
79. Sun, X.; Zheng, K. Electrochemical halogen-atom transfer alkylation via α-aminoalkyl radical activation of alkyl iodides. Nat. Commun. 2023, 14, 6825.
80. Peng, F.; Xiang, J.; Qin, H.; et al. Selective electrochemical oxidation of benzylic C-H to benzylic alcohols with the aid of imidazolium radical mediators. J. Am. Chem. Soc. 2023, 145, 23905-9.
81. Xiao, Y.; Xia, C.; Qian, Q.; et al. Halogen cocatalysis in electrocatalytic systems. Small 2025, 21, e05412.
82. Li, Z.; Wang, Q.; Gao, R.; Zhang, S. One- and two-electron carbon-halide bond activation at a phosphorus center. Angew. Chem. Int. Ed. 2025, 138, e21209.
83. Wang, D.; Kong, X.; Wang, Z.; Zhang, X.; Zhang, J.; Chen, Y. Dual-functional Fe3O4-decorated porous carbon nanosheets for kinetics-enhanced aqueous zinc-iodine batteries. Green. Carbon. 2025, 3, 382-92.
84. Fan, M.; Guo, J.; Fang, G.; et al. Microwave-pulse assisted synthesis of tunable ternary-doped 2D molybdenum carbide for efficient hydrogen evolution. Chem. Synth. 2024, 4, 36.
85. Li, Q.; Fang, G.; Wu, Z.; et al. Advanced microwave strategies facilitate structural engineering for efficient electrocatalysis. ChemSusChem 2024, 17, e202301874.
86. Wang, M.; Feng, Y.; Dai, J.; et al. Phase diversity driven mechanistic landscapes for nitrate to ammonia electrosynthesis. J. Hazard. Mater. 2026, 505, 141470.
87. Zhang, S.; Zhuo, G.; Wang, R.; et al. Polymer/MXene composite-based flexible pressure sensors: from mechanisms and structural designs to emerging applications. Polym. Sci. Technol. 2026, 2, 519-55.
88. Zhang, H.; Huang, Z.; Chen, C.; et al. Mid-infrared transparent materials: from mechanisms to cutting-edge applications. Nano. Micro. Lett. 2026, 18, 260.
89. Liu, Z. L.; Zhou, J. L.; Yuan, S. X.; Zhang, M. R.; Zhang, M.; Lu, T. B. Asymmetry-engineered g-C3N4 nanosheets with dual electronic-adsorption modulation for high-efficiency solar-driven H2O2 synthesis. Adv. Funct. Mater. 2025, 36, e23126.
90. Li, X.; Yang, S.; Yang, X.; et al. Modulating pore sizes and electronic properties of covalent organic polymers for the catalysis of two-electron oxygen reduction reaction in neutral media. ACS. Catal. 2024, 14, 13883-91.
91. Wang, Y.; Cheng, S.; Liu, Y.; et al. Fine-tuning electronic structure through phosphorus doping and defect engineering for selective 2e- ORR. ACS. Sustain. Chem. Eng. 2025, 13, 17445-54.
92. Wang, Y.; Bi, Y.; Xu, F.; et al. Synergistically crafted d-band center, d-orbital splitting manner and occupation in Fe2O3 anode for enhanced Ni-Fe battery performance. Nano. Energy. 2026, 151, 111846.
93. Pei, M. J.; Gao, X.; Shuai, Y. K.; et al. Machine learning-assisted molecular orbital insights into OER activity descriptors of component gradient Ni-based LDH electrocatalysts. Small 2025, 21, 2506357.
94. Nørskov, J. K.; Rossmeisl, J.; Logadottir, A.; et al. Origin of the overpotential for oxygen reduction at a fuel-cell cathode. J. Phys. Chem. B. 2004, 108, 17886-92.
95. Hammes-schiffer, S.; Stuchebrukhov, A. A. Theory of coupled electron and proton transfer reactions. Chem. Rev. 2010, 110, 6939-60.
96. He, Q.; Lin, D.; Yin, D.; Yang, C.; Chen, D.; Feng, X. Propene epoxidation with molecular oxygen: advancements from nanoparticle to single-atom catalysts. Smart. Mol. 2024, 2, e20240025.
97. Wang, S.; Luan, Y.; Ye, F.; et al. Cross-conjugated donor-acceptor polymers for high-performance organic electrochemical transistors. Poly. Sci. Technol. 2026, 2, 419-28.
98. Lei, B.; Zhou, G.; Gong, Z.; et al. Dynamically cyclic Fe2+/Fe3+ active sites as electron and proton-feeding centers boosting CO2 photoreduction powered by benzyl alcohol oxidation. Research 2024, 8, 0567.
99. Chen, X.; Lim, E. L.; Wei, Z. A brief overview of air-processed polycrystalline perovskite light-emitting diodes. Mater. Matter. 2026, 1, 3.
100. Yang, Y.; Song, T.; Ma, J.; et al. Synthesis of Ce2Sn2O7 pyrochlore and Ce2Sn2O8+x solid solution to support FeOx for simultaneous NH3-SCR and CO oxidation: study on the paramorphism effect. Smart. Mater. Devices. 2026, 2, 202612.
101. Zhang, C.; He, Z.; Qiao, L.; et al. Regulating the spin state of triple-atom catalysts for improved oxygen electrocatalysis in zinc-air batteries at subzero temperature. Innov. Mater. 2025, 3, 100131.
102. Zhang, J.; Feng, L.; Zhang, J.; et al. Electronic structure tailored covalent organic frameworks for synergistic adsorptive-photocatalytic gold recovery from complex electronic waste. Research 2025, 8, 1012.
103. Singh, D. K.; Natchimuthu Karuppusamy, M.; Shrivastava, A.; Palanisamy, T.; Sinha, I.; Ganesan, V. Sulfonic acid functionalization-boosted ultrafast, durable, and selective four-electron oxygen reduction reaction: evidenced by EC-SHINERS and DFT studies. ACS. Catal. 2023, 13, 4155-67.
104. Wang, C.; Wang, Z.; Lei, W.; Zhang, H.; Wang, Y. Enhancing the d-Electrocatalytic activity of MXene through defect engineering. Carbon. Energy. 2026, 8, e70148.
105. Chen, R.; Li, J.; Zhu, K.; et al. Electrocatalytic depolymerization of PET plastic fibers for circular textiles. Sustain. Eng. Novit. 2026, 2, 6.
106. Feng, Y.; Wang, M.; Zhang, H.; et al. Engineering electrocatalytic structures through molten salt-mediated mechanistic control. EcoEnergy 2025, 3, e70022.
107. He, Z.; Zhu, K.; Chen, R.; Zhou, L.; Ma, Y.; Wan, J. Engineering porous 2D materials for electrocatalytic small-molecule oxidation in decarbonized energy systems. Carb. Neutr. 2026, 5, 19.
108. Xie, L.; Liu, Y.; Li, S.; Shen, B.; Zhu, W. Phase and facet engineering for nanoscale catalyst discovery in electrochemical CO2 reduction. Nat. Synth. 2026, 5, 489-505.
109. Zhu, K.; Li, Z.; Chen, R.; Zhou, L.; Ma, Y.; Wan, J. Porous two dimensional architectures for high efficiency electrocatalytic urea oxidation. Smart. Mol. 2026, 4, e70057.
110. Jiao, J.; Wei, H.; Lei, Q.; et al. Recent progress on photoelectrochemical valorizations: a review of reactions, catalyst design, and future prospects. Sustain. Eng. Novit. 2026, 2, 5.
111. Jiang, Y.; Xie, Y.; Pan, Q.; et al. Universal taxol molecular binding engineering in dual-polarity MoS2 photodetector. Innov. Mater. 2026, 4, 100191.
112. Geng, Y.; Cao, Y.; Zhu, J. Graphene quantum dots: synthesis, properties, and applications in electroanalysis. Nano. Electrochem. Nano. Photochem. 2025, 1, 3.
113. Zhang, M.; Li, J.; Mao, W.; Zhang, W.; Chu, L. Air-processed FA-Cs perovskite scalable films without Pb0 defects for efficient inverted photovoltaic modules. J. Mater. Chem. A. 2026, 14, 14603-11.
114. Wei, R.; Li, S.; Li, A.; Lin, Y. Photo-/electrocatalytic reduction of CO2 based on ferroelectrics. Research 2025, 8, 0843.
115. Zhou, L.; Feng, J.; Zhu, K.; et al. Crystallographic symmetry-governed oxygen-defect chemistry in perovskite oxides for electrocatalytic water splitting. Mater. Matter. 2026, 1, 1.
116. Zhang, H.; Fan, M.; Liu, K.; et al. Unconventional trigonal PrNiO3 nanosheets for efficient electrocatalytic degradation of PET fibers. Nano. Mater. Sci. 2026, S2589965126000693.
117. Qin, S.; Chen, R.; Zhu, K.; et al. Electrocatalytic degradation strategies for plastic fibers with sustainable resource recovery potential. Coord. Chem. Rev. 2026, 558, 217806.
118. Chen, J.; Chu, L. AB epoxy encapsulation-induced transparency in perovskite films. Sci. China. Mater. 2025, 69, 570-4.
119. Ma, T.; Yang, M.; Feng, J.; et al. Spinel oxide crystallography governing lattice-coupled water-redox electrocatalysis. Smart. Mater. Devices. 2026, 2, 202546.
120. Zhang, S.; Liu, F.; Zhang, Y.; Zhou, W.; Chen, L.; Liu, Y. CeO2 facet-directed interfacial engineering in Ru1/CeO2 catalysts for efficient 2-butanol production from levulinic acid. Innov. Energy. 2026, 3, 100156.
121. Zhu, Z.; Zhang, H.; Hu, R.; Yao, Y.; Xu, W.; Wan, J. Thermally stable 2D YMnO3 enabling blue visible camouflage with mid-infrared transparency. Nat. Commun. 2026, 17, 8247.
122. Costentin, C. Electrochemical approach to the mechanistic study of proton-coupled electron transfer. Chem. Rev. 2008, 108, 2145-79.
123. Zhou, P.; Zhao, X.; Song, Y.; Ge, R.; Duan, H. pH-dependent electrochemical oxidation of 5-hydroxymethylfurfural: reaction mechanism, catalyst design, and reactor design across alkaline to acidic media. Smart. Mol. 2025, 4, e70027.
124. Tian, H.; Yao, M.; Guo, Y.; et al. Hydrogel electrolyte with regulated water activity and hydrogen bond network for ultra-stable zinc electrode. Adv. Energy. Mater. 2024, 15, 2403683.
125. Yu, M.; Wu, J.; Yin, G.; Jiao, F.; Yu, Z.; Qu, J. Dynamic regulation of hydrogen bonding networks and solvation structures for synergistic solar-thermal desalination of seawater and catalytic degradation of organic pollutants. Nano. Micro. Lett. 2024, 17, 48.
126. Zhang, S.; Gou, Q.; Chen, W.; et al. Co-regulating solvation structure and hydrogen bond network via bio-inspired additive for highly reversible zinc anode. Adv. Sci. 2024, 11, 2404968.
127. Anantharaj, S.; Pitchaimuthu, S.; Noda, S. A review on recent developments in electrochemical hydrogen peroxide synthesis with a critical assessment of perspectives and strategies. Adv. Colloid. Interface. Sci. 2021, 287, 102331.
128. Kim, J.; Kim, Y. E.; Je, M.; et al. A conformal titanyl phosphate amorphous overlayer for enhancing photoelectrochemical hydrogen peroxide production. J. Energy. Chem. 2023, 86, 399-408.
129. Wang, Y.; Sun, M.; Li, B.; Zhu, Y. Bubble engineering on flexible electrodes: from static interfaces to dynamic control. FlexMat 2026, flm2.70074.
130. Zhang, K.; Zhang, C.; Lin, Z.; et al. Carbon-based perovskite solar cell enables graded utilization of full solar spectrum beyond the photovoltaic S-Q limit via hybrid photovoltaics-photothermal conversion. Mater. Matter. 2026, 1, 2.
131. Liu, Q.; Zhu, Z.; Zhang, H.; et al. Advanced warming textiles for personalized thermal management through radiative, insulating, and electrothermal strategies. Mater. Today. Energy. 2026, 56, 102192.
132. Wu, J.; Zhang, S.; Gu, Q.; Zhang, Q. Recent progress in covalent organic frameworks for flexible electronic devices. FlexMat 2024, 1, 160-72.
133. Long, Y.; Chen, Z.; Xie, J.; et al. Sustainable plant-based electrodes for electrocatalytic conversion of small molecules: from biomass to functional electrodes. Exploration 2026, 6, 20250158.
134. Li, Y.; Lei, Q.; Hong, W. T.; Liu, X.; Xue, C.; Kim, J. K. Transition metal-based materials for electrochemical and photoelectrochemical carbon-free nitrogen cycling as H-carrier. Exploration 2025, 5, 20240245.
135. Fan, M.; Tian, H.; Wu, Z.; et al. Microwave shock synthesis of porous 2D non-layered transition metal carbides for efficient hydrogen evolution. SusMat 2024, 5, e252.
136. Liu, C. F.; Huang, J.; Wang, S.; Li, Y.; Lai, W. Y. Flexible organic crystals: from rational design to applications. FlexMat 2025, 2, 582-90.
137. Hu, Y.; Dai, L.; Li, B.; Yu, C.; Li, Z. Synergistic catalytic mechanism and performance regulation strategies between nanoparticles/clusters and single-atom sites. Mater. Futures. 2025, 4, 032102.
138. Yang, G.; Chen, F.; Fang, Q.; et al. Structural engineering of photoisomerizable covalent organic frameworks: design principles and functional applications. Polym. Sci. Technol. 2025, 1, 672-91.
139. Man, H.; Chen, G.; Wang, F.; et al. Entropy engineering activates Cu-Fe inertia center from prussian blue analogs with micro-strains for oxygen electrocatalysis in Zn-air batteries. Carbon. Energy. 2025, 7, e693.
140. Zhan, X.; Tong, X.; Ye, H.; et al. Atomically dispersed metal site materials for hydrogen energy utilization: theoretical and experimental study in fuel cells and water electrolysis. DeCarbon 2025, 7, 100091.
141. Wu, Z.; Yang, P.; Gao, M. Dynamic evolution of copper-based catalysts during CO2 electroreduction. Nano. Mater. Sci. 2026, 8, 687-702.
142. Hussain, M. S.; Ahmed, S.; Irshad, M.; et al. Recent engineering strategies for enhancing C2+ product formation in copper-catalyzed CO2 electroreduction. Nano. Mater. Sci. 2026, 8, 207-33.
143. Tan, X.; Liu, H.; Hou, T.; et al. Hardness augmentation engineering of TiFe2 with doping design and single-crystal realization. Innov. Mater. 2025, 3, 100140.
144. Zhang, J.; Liang, P.; Xu, X.; et al. Synergy of compress strain and antioxidant of platinum-copper for enhanced the oxygen reduction performance. Nano. Mater. Sci. 2025, 7, 105-12.
145. Shang, Z.; Chen, G.; Cui, Z.; Jiao, W.; Han, Y. Ordered modulation of electronic structure for efficient alkaline hydrogen oxidation. FlexMat 2025, 3, 93-100.
146. Zhang, B.; Han, B.; Guan, C.; Guo, Q.; Luo, Y.; Jiang, J. Highly selective oxygen reduction to H2O2 on π-d conjugated coordination polymers: the effect of coordination atoms. Chem. Eng. J. 2023, 460, 141688.
147. Liu, X.; Wang, J.; Ma, C.; et al. Dual-isolation effect of bismuth in non-noble BiNi alloys for enhanced performance in H2O2 electrosynthesis. ACS. Catal. 2025, 15, 1819-28.
148. Du, J.; Jiang, S.; Zhang, R.; et al. Generation of Pd-O for promoting electrochemical H2O2 production. ACS. Catal. 2023, 13, 6887-92.
149. Zhang, X.; Wang, C.; Chen, K.; et al. Optimizing the Pd sites in pure metallic aerogels for efficient electrocatalytic H2O2 production. Adv. Mater. 2023, 35, 2211512.
150. Lin, S. C.; Chang, C. W.; Tsai, M. H.; et al. Decreasing the O2-to-H2O2 kinetic energy barrier on dilute binary alloy surfaces with controlled configurations of isolated active atoms. Adv. Funct. Mater. 2024, 34, 2314281.
151. Hu, R.; Wei, L.; Xian, J.; et al. Microwave shock process for rapid synthesis of 2D porous La0.2Sr0.8CoO3 perovskite as an efficient oxygen evolution reaction catalyst. Acta. Phys. Chim. Sin. 2023, 39, 2212025.
152. Liu, R.; Kan, H.; Ma, X.; et al. Hydroxyl self-trapping strategy enables electrocatalysis at ampere-level current densities: kinetics-driven lattice oxygen activation for Cl--rich alkaline water electrooxidation. Carbon. Energy. 2025, 8, e70143.
153. Wang, J.; Xu, K.; Yu, Z.; et al. Lead-doped ruthenium-iridium oxide catalysts for durable acidic oxygen evolution in proton exchange membrane electrolyzers at 3 A cm-2. Mater. Futures. 2026, 5, 015101.
154. Wang, M.; Zhang, H.; Dai, J.; et al. Non-equilibrium construction of layered ruddlesden-popper La2NiO4 porous nanosheets for efficient urea electrooxidation. Carbon. Neutral. 2026, 5, e70132.
155. Xue, L.; Li, Y.; Deng, Y. Multicomponent porous metal oxide semiconductors for advanced gas sensing. Micro. Nano. Sci. 2025, 1, 2.
156. Zhang, S.; Gong, J.; Rong, Z.; Mao, W.; Chu, L. Blade coating large-area 3D/1D perovskite heterojunction films for effective synaptic memristors. Int. J. Miner. Metall. Mater. 2026, 33, 2778-86.
157. Kim, J.; Kwon, I. S.; Lim, J.; et al. Machine-learning-guided tungsten single atoms promote oxyhydroxides for noble-metal-free water electrolysis. Nat. Commun. 2026, 17, 2344.
158. Wang, T.; Xing, Z.; Wang, M.; et al. Bioinspired O2-evolution catalysts with proton-coupled electron transfer pathway for portable oxygen generation. Adv. Mater. 2025, 37, 2502102.
159. Hao, Y.; Li, J.; Cao, X.; et al. Origin of the universal potential-dependent organic oxidation on nickel oxyhydroxide. ACS. Catal. 2023, 13, 2916-27.
160. Liu, S.; Wu, L.; Tang, D.; et al. Transition from sequential to concerted proton-coupled electron transfer of water oxidation on semiconductor photoanodes. J. Am. Chem. Soc. 2023, 145, 23849-58.
161. Guo, X.; Qiu, L.; Li, M.; et al. Accelerating the generation of NiOOH by in-situ surface phosphating nickel sulfide for promoting the proton-coupled electron transfer kinetics of urea electrolysis. Chem. Eng. J. 2024, 483, 149264.
162. Yue, Y.; Zhu, K.; Li, X.; Ye, K. Porous metal-based catalysts for water electrolysis. Mater. Futures. 2025, 4, 032001.
163. Cheng, K.; Liu, C.; Wang, Y.; et al. Design of noble metal catalysts and reactors for the electrosynthesis of hydrogen peroxide. Acta. Phys. Chim. Sin. 2025, 41, 100112.
164. Yin, H.; Yuan, J.; Wang, J.; Hu, S.; Wang, P.; Xie, H. Crystalline nitrogen-doped-carbon anchored well-dispersed Fe3O4 nanoparticles for real-time scalable neutral H2O2 electrosynthesis. Energy. Environ. Sci. 2025, 18, 2231-42.
165. Hu, X.; Mei, G.; Chen, X.; Liu, J.; Xia, B. Y.; You, B. Simultaneous generation of H2O2 and formate by Co-electrolysis of water and CO2 over bifunctional Zn/SnO2 nanodots. Angew. Chem. Int. Ed. 2023, 62, e202304050.
166. Zhou, Y.; Xu, L.; Wu, J.; et al. The operation active sites of O2 reduction to H2O2 over ZnO. Energy. Environ. Sci. 2023, 16, 3526-33.
167. Deng, D.; Wang, Y.; Jiang, J.; et al. Indium oxide with oxygen vacancies boosts O2 adsorption and activation for electrocatalytic H2O2 production. Chem. Commun. 2024, 60, 9364-7.
168. Wondimu, T. H.; Yong, Z.; Shah, A. A.; et al. The recent progress of high-entropy layered double hydroxides and high-entropy amorphous materials for water electrocatalysis. DeCarbon 2025, 8, 100110.
169. Zhang, T.; Fan, H. J. Grafted superstructure renders catalyst stability in alkaline water oxidation. cScience 2025, 1, e70000.
170. Elbachraoui, F.; Aymé-Perrot, D.; Girault, H. H. Ionic transport aspects of water electrolysis in alkaline media. Research 2025, 8, 0788.
171. Nie, J.; Jiang, Q.; Sang, Z.; et al. Accelerating water dissociation to achieve ampere-level hydrogen peroxide electrosynthesis in brine and seawater. Nat. Commun. 2025, 16, 5895.
172. Zhang, T.; Wang, W.; Liu, W.; Guo, Z.; Liu, J. Residual ligand-functionalized ultrathin Ni(OH)2 via reconstruction for high-rate HO2- electrosynthesis. Nat. Commun. 2025, 16, 5240.
173. Qi, D.; Xu, J.; Zhou, Y.; et al. Cyclodextrin-supported Co(OH)2 clusters as electrocatalysts for efficient and selective H2O2 synthesis. Angew. Chem. Int. Ed. 2023, 62, e202307355.
174. Yu, K.; Yang, H.; Xu, J.; et al. Synergistic active heterostructure design for enhanced two electron oxygen reduction via chemical and electrochemical reconstruction of heterosulfides. Angew. Chem. Int. Ed. 2024, 63, e202408508.
175. Li, M.; Han, Z.; Hu, Q.; et al. Recent progress in solar-driven CO2 reduction to multicarbon products. Chem. Soc. Rev. 2024, 53, 9964-75.
176. Shi, Z.; Zhou, L.; Pan, S.; et al. Confinement phosphorization strategy unlocks FeP-N-C catalysts for highly stable zinc-air batteries. Carbon. Neutral. 2025, 4, e70065.
177. Tao, W.; He, G.; Feng, Q.; et al. Direct charge-transfer transition drives triplet generation and photon upconversion in 2D hybrid perovskites. J. Am. Chem. Soc. 2025, 147, 47280-8.
178. Hong, L.; Jing, C.; Zhang, Y.; Huang, H.; Jiang, Q.; Tang, J. Heterostructures with transition metal sulfides and transition metal phosphide: NiMnS/FeP achieve efficient seawater OER. J. Environ. Chem. Eng. 2025, 13, 115224.
179. Nishiwaki, E.; Kuo, D.; Cossairt, B. M. Utilizing the complexity of transition metal phosphide surfaces to tune nitrate reduction selectivity. Meet. Abstr. 2023, MA2023-02, 2778.
180. Guo, W.; Zhang, S.; Zhang, J.; et al. Accelerating multielectron reduction at CuxO nanograins interfaces with controlled local electric field. Nat. Commun. 2023, 14, 7383.
181. Li, H.; Shao, Y.; Zhang, Z.; et al. Understanding the unique selectivity of cobalt phthalocyanine in multielectron reduction of carbon dioxide. ACS. Catal. 2024, 15, 139-47.
182. Gui, T.; Wu, Z.; Li, J.; et al. Transition metal phosphides for seawater electrolysis: dynamic reconstruction, synergistic mechanisms and design paradigms. Adv. Funct. Mater. 2026, 36, e26293.
183. Wang, W.; Wang, A.; Xu, J.; et al. Surface reconstruction of pyrite-type transition metal sulfides during oxygen evolution reaction. J. Colloid. Interface. Sci. 2024, 657, 334-43.
184. Zhang, C.; Shan, P.; Zou, Y.; et al. Stable and high-yield hydrogen peroxide electrosynthesis from seawater. Nat. Sustain. 2025, 8, 542-52.
185. Che, H.; Wang, X.; Yue, H.; et al. Precise regulation of D-band centers inducing to high-efficiency dual-channel piezocatalytic H2O2 production. Adv. Funct. Mater. 2025, 36, e16979.
186. Kim, S. H.; Kim, J. H.; Park, B.; et al. Facet-controlled growth of molybdenum phosphide single crystals for efficient hydrogen peroxide synthesis. Adv. Mater. 2025, 37, 2500250.
187. Kim, J. H.; Lee, J. G.; Kim, C. S.; Choi, M. J. Ligand-driven electron-deficient cobalt pentlandite nanocrystals for efficient hydrogen peroxide electrosynthesis. Energy. Environ. Mater. 2024, 8, e12848.
188. Hu, C.; Zhang, G.; Duan, Q.; et al. Advances in surface-modification-driven functional MXenes for multidisciplinary applications. Smart. Mater. Devices. 2026, 2, 202601.
189. Cai, J.; Wu, Z.; Wang, S.; et al. Exploring advanced microwave strategy for the synthesis of two-dimensional energy materials. Appl. Phys. Rev. 2024, 11, 041320.
190. Luo, L.; Wang, Q.; Xiong, Y.; Mao, G.; Wang, H.; Lu, S. Ordered bimetallic Pt-based intermetallic catalysts enable highly efficient oxygen reduction reaction in zinc-air batteries. Carbon. Neutral. 2026, 5, e70114.
191. Ao, X.; Wu, F.; Yu, L.; Zhao, K.; Humayun, M.; Wang, C. Tailoring antiperovskite carbide for electrocatalysis hydrogen evolution applications. Chin. J. Struct. Chem. 2026, 45, 100851.
192. Kwon, H. R.; Yang, J. W.; Jang, H. W. Metal nitride catalysts for photoelectrochemical and electrochemical catalysis. Exploration 2025, 5, 20240013.
193. Tan, Z. W.; Agesta, N. F.; Yeo, R. Y. Z.; Foo, J. J.; Ong, W. J. Unlocking the potential of carbon nitride (CxNy) electrocatalysts in hydrogen evolution, oxygen evolution and overall water splitting. Exploration 2026, 6, 20240008.
194. Peng, S.; Wang, X.; Bi, J.; et al. Wafer-scale epitaxy of TiN nanoarrays on fluorophlogopites for flexible, refractory, and multifunctional plasmonic metamaterials. Innov. Mater. 2026, 4, 100189.
195. Yoo, R. M. S.; Ngozichukwu, B.; Yesudoss, D. K.; et al. Vibrational property tuning of MXenes revealed by sublattice N reactivity in polar and nonpolar solvents. J. Am. Chem. Soc. 2025, 147, 10104-17.
196. Li, N.; Huo, J.; Zhang, Y.; et al. Transition metal Carbides/Nitrides (MXenes): properties, synthesis, functional modification and photocatalytic application. Sep. Purif. Technol. 2024, 330, 125325.
197. Liu, J.; Zhang, Z.; Wang, X.; Han, C.; Yang, M. Triazolate-functionalized zirconium nitride for air-fed H2O2 production with industrial-level current density. J. Am. Chem. Soc. 2025, 147, 36618-25.
198. Li, B.; Ma, C.; Liu, X.; et al. Ordered Ni-Zn-C intermetallics enable highly selective two-electron oxygen reduction and efficient peroxone oxidation. Appl. Catal. B. Environ. Energy. 2026, 391, 126702.
199. Liu, J.; Zhang, Z.; Xu, Z.; et al. Tailoring oxygen adsorption on nickel nitride for selective 2e- ORR to hydrogen peroxide. Chem. Eng. J. 2025, 519, 165448.
200. Yin, J.; Jin, J.; Yin, Z.; et al. The built-in electric field across FeN/Fe3N interface for efficient electrochemical reduction of CO2 to CO. Nat. Commun. 2023, 14, 1724.
201. Du, J.; Han, G.; Zhang, X.; et al. Chaos of active site structure as a ladder to climbing the apex of the 2e- ORR volcano plot. J. Am. Chem. Soc. 2026, 148, 6905-14.
202. Sun, Y.; Fan, K.; Li, J.; et al. Boosting electrochemical oxygen reduction to hydrogen peroxide coupled with organic oxidation. Nat. Commun. 2024, 15, 6098.
203. Yan, M.; Wei, Z.; Gong, Z.; et al. Sb2S3-templated synthesis of sulfur-doped Sb-N-C with hierarchical architecture and high metal loading for H2O2 electrosynthesis. Nat. Commun. 2023, 14, 368.
204. Zhang, Z.; Zhou, F.; Wang, Y.; et al. Synergistic t2g-to-Ï€* electron transfer and nanotube engineering in spinal catalysts for ultra-efficient chloride evolution. Angew. Chem. Int. Ed. 2025, 64, e202513009.
205. Shao, L. Y.; Wang, Y.; Meng, J.; et al. Exclusive bridged *OCHO pathway activated by phenol-quinone conversion on the surface of Cu(OH)2 for highly selective formate production in CO2 electroreduction. Adv. Funct. Mater. 2025, 36, e14222.
206. Wang, Z.; Liu, D.; Xia, C.; et al. Tip carbon encapsulation customizes cationic enrichment and valence stabilization for low K+ acidic CO2 electroreduction. Nat. Commun. 2025, 16, 1754.
207. Bao, T.; Wu, Y.; Tang, C.; et al. Highly ordered conductive metal-organic frameworks with chemically confined polyoxometalate clusters: a dual-functional electrocatalyst for efficient H2O2 synthesis and biomass valorization. Adv. Mater. 2025, 37, 2500399.
208. Zou, Y.; Zhang, Y.; Zhang, C.; et al. Hydrogen-bonded organic framework@conductive metal-organic framework heterostructures for ampere-level hydrogen peroxide production. Nat. Commun. 2025, 16, 10908.
209. Sun, M.; Peng, Y.; Duan, C.; et al. Field-regulated dynamics at electrode/electrolyte interface toward efficient H2O2 generation via two-electron water oxidation. Adv. Funct. Mater. 2025, 36, e13578.
210. Tian, F.; Chang, W.; Liang, P.; et al. Charge redistribution dynamics in chalcogenide-stabilized cuprous electrocatalysts unleash ampere-scale partial current toward formate production. Nat. Commun. 2025, 16, 9426.
211. Ling, Z.; Yin, Y.; Ni, W.; et al. Efficient CO2-To-HCOOH conversion at industrial current density in strong acid via synergistic water activation. Adv. Funct. Mater. 2025, 36, e29166.
212. Shi, Y.; Liu, Y.; Dong, H.; et al. Operando nuclear magnetic resonance decodes alkali-tuned proton-electron relay boosting CO2-to-formate conversion. Nat. Commun. 2026, 17, 2136.
213. Chen, Q.; Li, B.; Gu, J.; et al. Selective electrosynthesis of nitrite from nitrate catalyzed by perovskite hydroxide CuSn(OH)6. ACS. Sustain. Chem. Eng. 2025, 13, 4046-54.
214. Mao, Z.; Zhang, J.; Tu, T.; et al. Cerium driven active site relocation in spinel Co3O4 enables stable chlorine evolution in acidic media. Nat. Commun. 2026, 17, 3763.
215. Zhao, S.; Li, H.; Dai, J.; et al. Selective electrosynthesis of chlorine disinfectants from seawater. Nat. Sustain. 2024, 7, 148-57.
216. Li, H.; Xin, X.; Sun, W.; Li, C.; Zhong, B. Regenerable surface-reconstructed silver mesh enables high-throughput electrocatalytic nitrate-to-nitrite conversion for near-perfect N2 selectivity in a tandem system. J. Colloid. Interface. Sci. 2026, 702, 139018.
217. Zhang, W.; Guo, F.; Gong, W.; et al. Electrochemical shortcut denitrification coupled with chemical diazotization for low-carbon nitrate wastewater treatment. Angew. Chem. Int. Ed. 2025, 65, e16226.
218. Guo, J.; Brimley, P.; Liu, M. J.; et al. Mass transport modifies the interfacial electrolyte to influence electrochemical nitrate reduction. ACS. Sustain. Chem. Eng. 2023, 11, 7882-93.
219. Li, H.; Wang, L.; Du, Q.; Liu, C.; Li, C.; Sun, W. Synergistic nitrate removal: coupling electrocatalysis and chemical reduction for exceptional nitrogen selectivity. Chem. Eng. J. 2024, 496, 153972.
220. Liu, Y.; Li, C.; Tan, C.; et al. Electrosynthesis of chlorine from seawater-like solution through single-atom catalysts. Nat. Commun. 2023, 14, 2475.
221. Adam, D. B.; Tsai, M.; Awoke, Y. A.; et al. Iodide oxidation reaction catalyzed by ruthenium-tin surface alloy oxide for efficient production of hydrogen and iodine simultaneously. ACS. Sustain. Chem. Eng. 2021, 9, 8803-12.
222. Ma, J.; Lee, W.; Kim, J. H.; et al. Leveraging the intermetal distance in dual-atom catalysts: revealing optimized synergistic interactions for CO2 electroreduction. ACS. Nano. 2025, 19, 18698-707.
223. Sun, W.; Liu, S.; Sun, H.; et al. Low-coordinated Ni single atom catalyst with carbon coordination for efficient CO2 electroreduction. Adv. Energy. Mater. 2025, 15, 2500283.
224. Ni, L.; Wang, P.; Wang, Y. Sustainable electro-fenton antifouling strategy simultaneously improves nitrogen-removal efficiency of anammox in membrane bioreactors. Environ. Sci. Technol. 2025, 59, 17545-57.
225. Zang, Y.; Liu, Y.; Lu, R.; et al. Tuning transition metal 3d spin state on single-atom catalysts for selective electrochemical CO2 reduction. Adv. Mater. 2025, 37, 2417034.
226. Liu, M.; Liu, S.; Xu, Q.; et al. Dual atomic catalysts from COF-derived carbon for CO2RR by suppressing HER through synergistic effects. Carbon. Energy. 2023, 5, e300.
227. Hamkins, K. S.; Vallez, L.; Zheng, X. Platinum-supported indium tin oxide catalyst for efficient H2O2 production via two-electron water oxidation reaction. ACS. Catal. 2025, 15, 11431-9.
228. Khan, R.; Chakraborty, J.; Singh Rawat, K.; et al. Super-oxidizing covalent triazine framework electrocatalyst for two-electron water oxidation to H2O2. Angew. Chem. Int. Ed. 2023, 62, e202313836.
229. Liu, Z.; Liu, Y.; Zhang, Y.; et al. Universal catalyst design framework for electrochemical hydrogen peroxide synthesis facilitated by local atomic environment descriptors. Angew. Chem. Int. Ed. 2025, 65, e18027.
230. Barasa Guta, C.; Gemechu Edao, H.; Bafe Dilebo, W.; et al. Novel electrocatalyst with abundant oxygen vacancies enabling efficient two-electron water oxidation reaction for H2O2 synthesis. Chem. Eng. J. 2024, 500, 156418.
231. Xiao, L.; Zhou, R.; Zhang, T.; et al. Porous indium nanocrystals on conductive carbon nanotube networks for high-performance CO2-to-formate electrocatalytic conversion. Energy. Environ. Mater. 2023, 7, e12656.
232. Jiang, Z.; Ren, S.; Cao, X.; et al. pH-universal electrocatalytic CO2 reduction with ampere-level current density on doping-engineered bismuth sulfide. Angew. Chem. Int. Ed. 2024, 63, e202408412.
233. Zhang, B.; Liu, W.; Liu, Z.; et al. Scalable and efficient electrochemical bromination of arenes with Faradaic efficiencies surpassing 90%. Nat. Commun. 2025, 16, 3052.
234. Tao, Z.; Wu, Z.; Wu, Y.; Wang, H. Activating copper for electrocatalytic CO2 reduction to formate via molecular interactions. ACS. Catal. 2020, 10, 9271-5.
235. Nie, J.; Li, Z.; Liu, W.; et al. Recent progress in oxygen reduction reaction toward hydrogen peroxide electrosynthesis and cooperative coupling of anodic reactions. Adv. Mater. 2025, 37, 2420236.
236. Wang, Q.; Ren, L.; Zhang, J.; et al. Recent progress on the catalysts and device designs for (photo)electrochemical on-site H2O2 production. Adv. Energy. Mater. 2023, 13, 2301543.
237. Xu, L.; Nan, X.; Yu, J. C. Recent progress on graphitic carbon nitride-based photocatalysts for hydrogen peroxide synthesis. Exploration 2026, 6, 20240484.
238. Chen, J.; Ma, Q.; Zheng, X.; Fang, Y.; Wang, J.; Dong, S. Kinetically restrained oxygen reduction to hydrogen peroxide with nearly 100% selectivity. Nat. Commun. 2022, 13, 2808.
239. Zhang, C.; Lu, R.; Liu, C.; et al. Trimetallic sulfide hollow superstructures with engineered d-band center for oxygen reduction to hydrogen peroxide in alkaline solution. Adv. Sci. 2022, 9, 2104768.
240. Yang, M.; Zhao, Z.; Zhi, T.; et al. Multiscale catalyst engineering for stable, selective, and carbon-neutral industrial hydrogen peroxide electrosynthesis. Carbon. Neutral. 2025, 4, e70017.
241. Huang, H.; Sun, F.; Luo, Z.; et al. MOF@MOF hierarchical heterotructures for enhanced photocatalytic H2O2 production and furfuryl alcohol oxidation. Chin. J. Struct. Chem. 2025, 44, 100717.
242. Zhang, H.; Li, H.; Zhang, X.; Yu, S.; Wang, S.; Sun, G. Enhanced metal-support interaction of nitrogen-doped carbon supported Pt nanoparticles with high activity for electrocatalytic oxygen reduction reaction. Carb. Neutrality. 2025, 4, 10.
243. Kang, D.; Zhang, C.; Wang, X.; et al. Efficient atomically dispersed Fe catalysts with robust three-phase interface for stable seawater-based zinc-air batteries. Green. Carbon. 2025, 3, 1-10.
244. Liu, J.; Li, S.; Li, H.; Wan, X.; Shui, J. Oxophilic Yb2O3 nanoparticles as radical scavengers to enhance the durability of Fe-N-C oxygen reduction catalysts. Smart. Mol. 2026, 4, e70049.
245. Li, L.; Qin, N.; Ma, H.; et al. Rational design of nitrogen and fluorine co-doped metal-free porous carbons electrocatalysts for highly efficient oxygen reduction and zinc-air batteries. Carb. Neutrality. 2025, 4, 1.
246. Liu, R.; Wang, C.; Yan, Y.; Wang, R.; Chen, G. Reversed charge transfer to modulate the d-band center of Pd for efficient direct H2O2 synthesis. ACS. Catal. 2024, 14, 3955-65.
247. Hu, J.; Shang, W.; Xin, C.; et al. Uncovering dynamic edge-sites in atomic Co-N-C electrocatalyst for selective hydrogen peroxide production. Angew. Chem. Int. Ed. 2023, 62, e202304754.
248. Wang, J.; Huang, J.; Jia, C.; et al. Catalyst-engineered proton transfer pathways for selective hydrogen peroxide electrosynthesis in solid-state electrolytes. Angew. Chem. Int. Ed. 2025, 64, e202510645.
249. Wang, Y.; Duan, P.; Liao, Y.; et al. Differentiating interfacial water structures via alkali metal cation promotor for H2O2 electrosynthesis in acid. Nat. Commun. 2026, 17, 4973.
250. Cheng, F.; Liu, Y.; Zhao, Z.; et al. Enhanced proton-feeding kinetics of metal-organic framework toward industrial-level H2O2 electrosynthesis for sustainable bleaching. Nat. Commun. 2025, 16, 10183.
251. Xie, H.; Nie, G.; Fang, Y.; et al. Synergistically boosting charge separation and surface activity for efficient solar-powered cathodic metal protection. Carb. Neutrality. 2026, 5, 1.
252. Liu, H.; Luo, G.; Han, Q.; et al. Generation of hydrogen peroxide by using solid CaCO3 suspension via two-electron water oxidation. Chem. Eng. J. 2025, 518, 164498.
253. Zhou, Q.; Yan, Z.; Lan, Y.; et al. A general strategy to enhance hydrogen peroxide generation via two-electron water oxidation by antimony modification for removal of triethyl phosphate and hexavalent chromium. Appl. Catal. B. Environ. 2024, 342, 123427.
254. Lei, Y.; Gao, L.; Ling, C.; Guo, S. Q. Electrosynthesis of hydrogen peroxide via two-electron water oxidation reaction: mechanistic insights, materials design, and practical feasibility. Chem. Eng. J. 2026, 535, 175221.
255. Feng, J.; Chen, J.; Xu, F.; et al. Boosting photocatalytic H2O2 production via two-electron water oxidation over Ag decorated on ZIF-8 derived ZnO nanostructure. Chem. Eng. J. 2026, 538, 176632.
256. Kim, C.; Park, S. O.; Kwak, S. K.; Xia, Z.; Kim, G.; Dai, L. Concurrent oxygen reduction and water oxidation at high ionic strength for scalable electrosynthesis of hydrogen peroxide. Nat. Commun. 2023, 14, 5822.
257. Zhang, X.; Wan, Y.; Wen, Y.; et al. SnSe nanosheets with Sn vacancies catalyse H2O2 production from water and oxygen at ambient conditions. Nat. Catal. 2025, 8, 465-75.
258. Xu, J.; Zhang, Q.; Gao, X.; et al. Highly efficient FeIII-initiated self-cycled fenton system in piezo-catalytic process for organic pollutants degradation. Angew. Chem. Int. Ed. 2023, 62, e202307018.
259. Li, L.; Hu, Z.; Kang, Y.; et al. Electrochemical generation of hydrogen peroxide from a zinc gallium oxide anode with dual active sites. Nat. Commun. 2023, 14, 1890.
260. Tian, G. Disentangling activity-selectivity trade-offs in CO2 conversion through multifunctional catalytic systems. cScience 2026, 2, e70020.
261. Fang, G.; Liu, K.; Fan, M.; et al. Unveiling the electron configuration-dependent oxygen evolution activity of 2D porous Sr-substituted LaFeO3 perovskite through microwave shock. Carbon. Neutral. 2023, 2, 709-20.
262. Yan, F.; Bai, B.; Huang, J.; Xu, J.; Fu, Y. Rational design of transition-metal dual-atom catalysts: exploiting neighboring effects for efficient CO2 Reduction. Carbon. Neutral. 2026, 5, e70146.
263. Wang, S.; Yang, Y.; Xu, W.; et al. Crucial role of hydroxyl in CO selectivity for integrated CO2 capture and electrocatalytic reduction. Carb. Neutrality. 2026, 5, 4.
264. Lu, R.; Liu, Y.; Wang, Z. Advances in the understanding of selective CO2 reduction catalysis. EcoEnergy 2024, 2, 695-713.
265. Xing, L. Electrified CO2-to-methanol pathways: a time-resolved roadmap from deployment to disruption. cScience 2026, 2, e70018.
266. Liu, W.; Duan, X.; Jiang, L.; et al. Compressed carbon dioxide energy storage in salt caverns holds promise for China's hard-to-abate sectors. Innov. Energy. 2025, 2, 100065.
267. Zhang, H.; Wang, X.; Chen, C.; et al. Selective CO2-to-formic acid electrochemical conversion by modulating electronic environment of copper phthalocyanine with defective graphene. Chin. J. Struct. Chem. 2023, 42, 100089.
268. Mang, C.; Luo, S.; Luo, J.; Li, H.; Li, G.; Jiang, T. ZnO@cryptomelane-type MnO2 heterostructures for high-efficiency photocatalytic CO2 reduction: synergistic charge transfer and reaction pathway elucidation. cScience 2026, 2, e70012.
269. Peng, C.; Yan, M.; Liu, Z. Regulating oxygen defects over CeO2 via rare earth oxide doping for Pt-catalyzed oxidative dehydrogenation of propane with carbon dioxide. Smart. Mater. Devices. 2026, 2, 202604.
270. Du, J. H.; Liu, Z.; Sheng, T.; et al. Host-guest metal interaction in Cu-In single atom alloy switching electrocatalytic CO2 reduction pathway. Angew. Chem. Int. Ed. 2025, 64, e202512970.
271. Chen, F.; Elgazzar, A.; Pecaut, S.; et al. Electrochemical nitrate reduction to ammonia with cation shuttling in a solid electrolyte reactor. Nat. Catal. 2024, 7, 1032-43.
272. Gu, X.; Zhang, J.; Guo, S.; et al. Tiara Ni clusters for electrocatalytic nitrate reduction to ammonia with 97% faradaic efficiency. J. Am. Chem. Soc. 2025, 147, 22785-95.
273. Guo, C.; Guo, M.; Zhang, Y.; Han, S.; Yu, Y. Lattice hydrogen involved electrocatalytic nitrate reduction to hydroxylamine. J. Am. Chem. Soc. 2025, 147, 14869-77.
274. Wu, Z.; Song, Y.; Guo, H.; et al. Tandem catalysis in electrocatalytic nitrate reduction: unlocking efficiency and mechanism. Interd. Mater. 2024, 3, 245-69.
275. Li, J.; Wang, Y.; Ji, X.; et al. Unraveling tandem catalytic sites for electrocatalytic nitrate reduction to ammonia. Adv. Energy. Mater. 2025, 16, e03822.
276. Zhang, H.; Fang, K.; Yang, J.; et al. Strategies and applications of electrocatalytic nitrate reduction towards ammonia. Coord. Chem. Rev. 2024, 506, 215723.
277. Murphy, E.; Liu, Y.; Matanovic, I.; et al. Elucidating electrochemical nitrate and nitrite reduction over atomically-dispersed transition metal sites. Nat. Commun. 2023, 14, 4554.
278. Jiang, H.; Chen, G. F.; Savateev, O.; et al. Enabled efficient ammonia synthesis and energy supply in a zinc-nitrate battery system by separating nitrate reduction process into two stages. Angew. Chem. Int. Ed. 2023, 62, e202218717.
279. Liang, N.; Choi, W.; Suk, Han. D.; Park, H. Electrocatalytic conversion of ethylene to ethylene oxide mediated by halide oxidation: chloride vs. bromide vs. iodide. Chem. Eng. J. 2024, 494, 153042.
280. Li, R.; Zhang, L.; Qin, X.; et al. Efficient photocatalytic two-electron halide oxidation over p-block metal Bi- and Sb-based catalysts. ACS. Catal. 2025, 15, 2171-9.
281. Pang, H.; Ji, X.; Liu, Y.; et al. Tailoring Se-mediated Co-Co dual-atom sites for oxygen and iodide electrocatalysis toward high-efficiency and ultradurable zinc-air/iodide hybrid batteries. Carbon. Energy. 2026, 8, e70221.
282. Maiti, A.; Pachfule, P.; Biswas, A.; Mahalingam, V.; Bhunia, A. Controlled heterogeneous electrocatalytic oxidation of carboxylates and halides for the synthesis of novel chemicals. ChemCatChem 2025, 17, e202500069.
283. Li, X.; Liu, T.; Li, P.; et al. Aqueous alkaline zinc-iodine battery with two-electron transfer. ACS. Nano. 2025, 19, 2900-8.
284. Xu, Y.; Xie, C.; Li, T.; Li, X. A high energy density bromine-based flow battery with two-electron transfer. ACS. Energy. Lett. 2022, 7, 1034-9.
285. Chen, Z.; Wang, Y.; Wei, Z.; et al. Highly efficient chlorine fixation based on organic selenium for 3.7-V aqueous batteries. J. Am. Chem. Soc. 2026, 148, 11531-9.
286. Lu, H.; Zhuang, X.; Ding, J.; et al. Ion-defect dual management for achieving efficient air-processed perovskite solar cells with certified efficiency 27.1%. Adv. Mater. 2026, 38, e17596.
287. Li, X.; Wang, Y.; Lu, J.; et al. Constructing static two-electron lithium-bromide battery. Sci. Adv. 2024, 10, eadl0587.





